This is the new version of Wastewater & Sludge Guidelines
This version (V2) is published and available to prepare for. It will replace the active version (V1) and take effect from 01 Dec 2026. Until then, continue using Wastewater & Sludge Guidelines V1. View Changelog
Untreated wastewater Requirements
Untreated wastewater: ZDHC MRSL Parameters
| Substance / Parameter | CAS NO | Foundational Limit | Progressive Limit | Aspirational Limit | Reporting Limit | Test Method |
|---|---|---|---|---|---|---|
| Alkylphenol (AP) and Alkylphenol Ethoxylates (APEOs): including all isomers | ||||||
| Nonylphenol (NP), mixed isomers |
104-40-5
11066-49-2
25154-52-3
84852-15-3
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
5
μg/L
Textile :
5
μg/L
Footwear :
5
μg/L
|
ISO 18857-2
Modified dichloromethane extraction
ASTM D7065
GC-MS or LC-MS/MS
ASTM D7742
GB/T 31414-2105
ISO 18254-1
ISO 18218-1 2105 (leather)
|
| Nonylphenol ethoxylates (NPEO) |
127087-87-0
26027-38-3
37205-87-1
68412-54-4
9016-45-9
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
5
μg/L
Leather :
5
μg/L
Footwear :
5
μg/L
|
ASTM D7742
ISO 18857-2
Modified dichloromethane extraction
ASTM D7065
GC-MS or LC-MS/MS
ISO 18218-1 2105 (leather)
ISO 18254-1
GB/T 31414-2105
|
| Octylphenol (OP), mixed isomers |
140-66-9
1806-26-4
27193-28-8
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
5
μg/L
Textile :
5
μg/L
Footwear :
5
μg/L
|
ISO 18857-2
GC-MS or LC-MS/MS
ASTM D7065
(modified dichloromethane extraction)
ASTM D7742
ISO 18254-1
ISO 18218-1 2105 (leather)
GB/T 31414-2105
|
| Octylphenol ethoxylates (OPEO) |
68987-90-6
9002-93-1
9036-19-5
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
5
μg/L
Textile :
5
μg/L
Footwear :
5
μg/L
|
ISO 18857-2
modified dichloromethane extraction
ASTM D7065
GC-MS or LC-MS/MS
ASTM D7742
ISO 18254-1
ISO 18218-1 2105 (leather)
GB/T 31414-2105
|
| Anti-microbials and Biocides | ||||||
| Dimethylfumarate (DMFu) |
624-49-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Leather :
50
μg/L
Footwear :
50
μg/L
|
EPA 8270
Analysis by GC-MS
|
| O-Phenylphenol(+salts) |
90-43-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
100
μg/L
Leather :
(Sample and report)
μg/L
Footwear :
100
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
An alternative method of solvent extraction and derivatisation are included
GBT 20386-2006 6.1
BS EN 12673
ISO 17070 of chlorophenols
|
| Permethrin |
52645-53-1
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
500
μg/L
Textile :
500
μg/L
Footwear :
500
μg/L
|
USEPA 8270E
Solvent extraction, followed by GC-MS
ISO 14154:2005
An alternate method, without derivatisation and determination by LCMS/LCMSMS, is also possible
EPA 8081
EPA 3550C
GBT 20386-2006 6.1
USEPA 8270E
Solvent extraction followed by GC-MS/MS
DIN 38407- 37
Solvent extraction followed by GC-MS/MS
GB/T 18412.4-2006
|
| Triclosan |
3380-34-5
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
100
μg/L
Textile :
100
μg/L
Footwear :
100
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
An alternative method of solvent extraction and derivatisation are included
GBT 20386-2006 6.1
BS EN 12673
GBT 20386-2006 6.1
|
| Chlorinated Paraffins | ||||||
| Medium-chain Chlorinated Paraffins (MCCPs)(C14-C17) |
85535-85-9
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
500
μg/L
Textile :
500
μg/L
Footwear :
500
μg/L
|
EPA 3510
ISO 18219-2:2021
Method for MCCP with GC-MS(NCI) or LC-MS/MS
ISO 12010 for textiles
|
| Short-chain Chlorinated Paraffins (SCCPs) (C10-C13) |
85535-84-8
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
25
μg/L
Textile :
25
μg/L
Footwear :
25
μg/L
|
EPA 3510
ISO 18219-1:2021
Method for SCCP with GC-MS(NCI) or LC-MS/MS
ISO 12010:2019
Method for SCCP with GC-MS(NCI) or LC-MS/MS
ISO 12010 for textiles
|
| Chlorobenzenes and Chlorotoluenes | ||||||
| Other isomers of mono-, di-, tri-, tetra- and penta- chlorotoluene |
1006-31-1
1006-32-2
106-43-4
108-41-8
118-69-4
19398-61-9
2077-46-5
21472-86-6
25186-47-4
32768-54-0
6639-30-1
875-40-1
877-11-2
95-49-8
95-73-8
95-75-0
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.2
μg/L
Leather :
0.2
μg/L
Footwear :
0.2
μg/L
|
EPA 8021 B
EPA 8270 D
EPA 8540 C
ASTM D 5369 - 93
DIN 38407-37
HJ 699- 2014
|
| Other isomers of mono-, di-, tri-, tetra-, penta- and hexa- Chlorobenzene |
106-46-7
108-70-3
108-90-7
118-74-1
120-82-1
23749-65-7
541-73-1
608-93-5
634-66-2
634-90-2
7359-72-0
87-61-6
95-94-3
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.2
μg/L
Leather :
0.2
μg/L
Footwear :
0.2
μg/L
|
EPA 8270 D
Purge and Trap, Head Space Dichloromethane extraction followed by GC-MS
EPA 8270E
Purge and Trap, Head Space Dichloromethane extraction followed by GC-MS
EPA 8021 B
EPA 8270 D
EPA 8540C
ASTM D 5369 - 93
DIN 38407- 37
HJ 699- 2014
|
| Chlorophenols | ||||||
| 2,3,4,5-Tetrachlorophenol |
4901-51-3
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.5
μg/L
Textile :
0.5
μg/L
Footwear :
0.5
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
The procedure of solvent extraction and derivatisation are included
EN 12673
US EPA 1653 + US EPA 8270D
|
| 2,3,4,6-Tetrachlorophenol |
58-90-2
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.5
μg/L
Textile :
0.5
μg/L
Footwear :
0.5
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
The procedure of solvent extraction and derivatisation are included
US EPA 1653 + US EPA 8270D
EN 12673
|
| 2,3,4-Trichlorophenol |
15950-66-0
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.5
μg/L
Textile :
0.5
μg/L
Footwear :
0.5
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
The procedure of solvent extraction and derivatisation are included
EN 12673
US EPA 1653 + US EPA 8270D
|
| 2,3,5,6-Tetrachlorophenol |
935-95-5
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.5
μg/L
Textile :
0.5
μg/L
Footwear :
0.5
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
The procedure of solvent extraction and derivatisation are included
EN 12673
US EPA 1653 + US EPA 8270D
|
| 2,3,5-Trichlorophenol |
933-78-8
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.5
μg/L
Textile :
0.5
μg/L
Footwear :
0.5
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
The procedure of solvent extraction and derivatisation are included
EN 12673
US EPA 1653 + US EPA 8270D
|
| 2,3,6-Trichlorophenol |
933-75-5
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.5
μg/L
Textile :
0.5
μg/L
Footwear :
0.5
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
The procedure of solvent extraction and derivatisation are included
EN 12673
US EPA 1653 + US EPA 8270D
|
| 2,3-Dichlorophenol |
576-24-9
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.5
μg/L
Textile :
0.5
μg/L
Footwear :
0.5
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
The procedure of solvent extraction and derivatisation are included
EN 12673
US EPA 1653 + US EPA 8270D
|
| 2,4,5-Trichlorophenol |
95-95-4
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.5
μg/L
Textile :
0.5
μg/L
Footwear :
0.5
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
The procedure of solvent extraction and derivatisation are included
EN 12673
US EPA 1653 + US EPA 8270D
|
| 2,4,6-Trichlorophenol |
88-06-2
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.5
μg/L
Textile :
0.5
μg/L
Footwear :
0.5
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
The procedure of solvent extraction and derivatisation are included
EN 12673
US EPA 1653 + US EPA 8270D
|
| 2,4-Dichlorophenol |
120-83-2
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.5
μg/L
Textile :
0.5
μg/L
Footwear :
0.5
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
The procedure of solvent extraction and derivatisation are included
EN 12673
US EPA 1653 + US EPA 8270D
|
| 2,5-Dichlorophenol |
583-78-8
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.5
μg/L
Textile :
0.5
μg/L
Footwear :
0.5
μg/L
|
USEPA 8270E
BS EN 12673-1999
The procedure of solvent extraction and derivatisation are included
EN 12673
US EPA 1653 + US EPA 8270D
|
| 2,6-Dichlorophenol |
87-65-0
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.5
μg/L
Textile :
0.5
μg/L
Footwear :
0.5
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
The procedure of solvent extraction and derivatisation are included
EN 12673
US EPA 1653 + US EPA 8270D
|
| 2-Chlorophenol |
95-57-8
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.5
μg/L
Textile :
0.5
μg/L
Footwear :
0.5
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
The procedure of solvent extraction and derivatisation are included
EN 12673
US EPA 1653 + US EPA 8270D
|
| 3,4,5-Trichlorophenol |
609-19-8
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.5
μg/L
Textile :
0.5
μg/L
Footwear :
0.5
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
The procedure of solvent extraction and derivatisation are included
EN 12673
US EPA 1653 + US EPA 8270D
|
| 3,4-Dichlorophenol |
95-77-2
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.5
μg/L
Textile :
0.5
μg/L
Footwear :
0.5
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
The procedure of solvent extraction and derivatisation are included
EN 12673
US EPA 1653 + US EPA 8270D
|
| 3,5-Dichlorophenol |
591-35-5
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.5
μg/L
Textile :
0.5
μg/L
Footwear :
0.5
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
The procedure of solvent extraction and derivatisation are included
EN 12673
US EPA 1653 + US EPA 8270D
|
| 3-Chlorophenol |
108-43-0
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.5
μg/L
Textile :
0.5
μg/L
Footwear :
0.5
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
The procedure of solvent extraction and derivatisation are included
EN 12673
US EPA 1653 + US EPA 8270D
|
| 4-Chlorophenol |
106-48-9
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.5
μg/L
Textile :
0.5
μg/L
Footwear :
0.5
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
The procedure of solvent extraction and derivatisation are included
EN 12673
US EPA 1653 + US EPA 8270D
|
| Pentachlorophenol (PCP) |
87-86-5
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.5
μg/L
Textile :
0.5
μg/L
Footwear :
0.5
μg/L
|
USEPA 8270E
Solvent extraction, derivatisation with KOH, acetic anhydride followed by GC-MS
BS EN 12673-1999
The procedure of solvent extraction and derivatisation are included
EN 12673
US EPA 1653 + US EPA 8270D
|
| Dyes – Carcinogenic or Equivalent Concern | ||||||
| Basic Violet 3 with > 0.1% of Michler´s Ketone |
548-62-9
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
500
μg/L
Textile :
500
μg/L
Footwear :
500
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
EPA 8321 B, Direct Injection method LC/MS/MS.
DIN 54231
EPA 8021 B
|
| C.I. Acid Red 26 |
3761-53-3
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
500
μg/L
Textile :
500
μg/L
Footwear :
500
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
EPA 8321 B, Direct Injection method LC/MS/MS.
|
| C.I. Acid Violet 49 |
1694-09-03
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
500
μg/L
Textile :
500
μg/L
Footwear :
500
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
EPA 8321 B, Direct Injection method LC/MS/MS.
|
| C.I. Basic Blue 26 (with Michler’s Ketone > 0.1%) |
2580-56-5
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
500
μg/L
Textile :
500
μg/L
Footwear :
500
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
EPA 8321 B, Direct Injection method LC/MS/MS.
|
| C.I. Basic Green 4 (Malachite Green Chloride) |
569-64-2
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
500
μg/L
Textile :
500
μg/L
Footwear :
500
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
|
| C.I. Basic Green 4 (Malachite Green Oxalate) |
2437-29-8
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
500
μg/L
Textile :
500
μg/L
Footwear :
500
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
EPA 8321 B, Direct Injection method LC/MS/MS.
|
| C.I. Basic Green 4 (Malachite Green) |
10309-95-2
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
500
μg/L
Textile :
500
μg/L
Footwear :
500
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
|
| C.I. Basic Green 4 leuco base |
129-73-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
500
μg/L
Leather :
500
μg/L
Footwear :
500
μg/L
|
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
EPA 8321 B, Direct Injection method LC/MS/MS.
|
| C.I. Basic Red 9 |
569-61-9
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
500
μg/L
Textile :
500
μg/L
Footwear :
500
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
EPA 8321 B, Direct Injection method LC/MS/MS.
|
| C.I. Basic Violet 14 |
632-99-5
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
500
μg/L
Textile :
500
μg/L
Footwear :
500
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
EPA 8321 B, Direct Injection method LC/MS/MS.
|
| C.I. Direct Black 38 |
1937-37-7
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
500
μg/L
Textile :
500
μg/L
Footwear :
500
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
EPA 8321 B, Direct Injection method LC/MS/MS.
|
| C.I. Direct Blue 6 |
2602-46-2
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
500
μg/L
Textile :
500
μg/L
Footwear :
500
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
EPA 8321 B, Direct Injection method LC/MS/MS.
|
| C.I. Direct Red 28 |
573-58-0
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
500
μg/L
Textile :
500
μg/L
Footwear :
500
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
EPA 8321 B, Direct Injection method LC/MS/MS.
|
| C.I. Disperse Blue 1 |
2475-45-8
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
500
μg/L
Leather :
500
μg/L
Footwear :
500
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
EPA 8321 B, Direct Injection method LC/MS/MS.
|
| C.I. Disperse Blue 3 |
2475-46-9
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
500
μg/L
Leather :
500
μg/L
Footwear :
500
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
EPA 8321 B, Direct Injection method LC/MS/MS.
|
| C.I. Disperse Orange 11 |
82-28-0
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
500
μg/L
Leather :
500
μg/L
Footwear :
500
μg/L
|
Liquid extraction LC-MS
EPA 8321 B, Direct Injection method LC/MS/MS.
US EPA 1653 + US EPA 8270D
|
| Dyes – Disperse (Allergenic) | ||||||
| Disperse Blue 102 |
12222-97-8
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
USEPA 8321B
|
| Disperse Blue 106 |
12223-01-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
USEPA 8321B
|
| Disperse Blue 124 |
61951-51-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
USEPA 8321B
|
| Disperse Blue 26 |
3860-63-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
USEPA 8321B
|
| Disperse Blue 35 |
12222-75-2
56524-77-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
USEPA 8321B
|
| Disperse Blue 7 |
3179-90-6
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
USEPA 8321B
|
| Disperse Brown 1 |
23355-64-8
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
USEPA 8321B
|
| Disperse Orange 1 |
2581-69-3
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
USEPA 8321B
|
| Disperse Orange 3 |
730-40-5
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
USEPA 8321B
|
| Disperse Orange 37/59/76 |
13301-61-6
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
USEPA 8321B
|
| Disperse Red 1 |
2872-52-8
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
|
| Disperse Red 11 |
2872-48-2
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
USEPA 8321B
|
| Disperse Red 17 |
3179-89-3
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
USEPA 8321B
|
| Disperse Yellow 1 |
119-15-3
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
USEPA 8321B
|
| Disperse Yellow 3 |
2832-40-8
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
USEPA 8321B
|
| Disperse Yellow 39 |
12236-29-2
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
|
| Disperse Yellow 49 |
54824-37-2
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
USEPA 8321B
|
| Disperse Yellow 9 |
6373-73-5
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
Direct aqueous injection followed by LC/MS/MS (based on DIN 54231:2022)
US EPA 1653 + US EPA 8270D
USEPA 8321B
|
| Flame Retardants | ||||||
| 2,2-Bis(bromomethyl)-1,3-propanediol (BBMP) |
3296-90-0
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 17881 Part 2 (FR on textile)
|
| Bis(2,3-dibromopropyl) phosphate (BDBPP) |
5412-25-9
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Boric acid |
10043-35-3
11113-50-1
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
500
μg/L
Leather :
500
μg/L
Footwear :
500
μg/L
|
determined as total boron via ICP
|
| Decabromobiphenyl (DecaBB) |
13654-09-6
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Decabromodiphenyl ether (DecaBDE) |
1163-19-5
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Diboron trioxide |
1303-86-2
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
500
μg/L
Leather :
500
μg/L
Footwear :
500
μg/L
|
determined as total boron via ICP
|
| Dibromobiphenyls (DiBB) |
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Dibromopropylether |
21850-44-2
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Disodium octaborate |
12008-41-2
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
500
μg/L
Leather :
500
μg/L
Footwear :
500
μg/L
|
determined as total boron via ICP
|
| Disodium tetraborate, anhydrous |
1303-96-4
1330-43-4
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
500
μg/L
Leather :
500
μg/L
Footwear :
500
μg/L
|
determined as total boron via ICP
|
| Heptabromodiphenyl ether (HeptaBDE) |
68928-80-3
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Hexabromocyclodecane (HBCDD) |
3194-55-6
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Hexabromodiphenyl ether (HexaBDE) |
36483-60-0
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Monobromobiphenyls (MonoBB) |
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
(Dichloromethane extraction GC-MS or LC-MS/MS)
ISO 22032
(Dichloromethane extraction GC-MS or LC-MS/MS)
USEPA 527
(Dichloromethane extraction GC-MS or LC-MS/MS)
USEPA 8321B
(Dichloromethane extraction GC-MS or LC-MS/MS)
|
| Monobromodiphenylethers (MonoBDEs) |
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
(Dichloromethane extraction GC-MS or LC-MS/MS)
ISO 22032
(Dichloromethane extraction GC-MS or LC-MS/MS)
USEPA 527
(Dichloromethane extraction GC-MS or LC-MS/MS)
USEPA 8321B
(Dichloromethane extraction GC-MS or LC-MS/MS)
|
| Nonabromobiphenyls (NonaBB) |
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
(Dichloromethane extraction GC-MS or LC-MS/MS)
ISO 22032
(Dichloromethane extraction GC-MS or LC-MS/MS)
USEPA 527
(Dichloromethane extraction GC-MS or LC-MS/MS)
USEPA 8321B
(Dichloromethane extraction GC-MS or LC-MS/MS)
|
| Nonabromodiphenyl ether (NonaBDE) |
63936-56-1
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
(Dichloromethane extraction GC-MS or LC-MS/MS)
ISO 22032
(Dichloromethane extraction GC-MS or LC-MS/MS)
USEPA 527
(Dichloromethane extraction GC-MS or LC-MS/MS)
USEPA 8321B
(Dichloromethane extraction GC-MS or LC-MS/MS)
|
| Octabromobiphenyls (OctaBB) |
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
(Dichloromethane extraction GC-MS or LC-MS/MS)
ISO 22032
(Dichloromethane extraction GC-MS or LC-MS/MS)
USEPA 527
(Dichloromethane extraction GC-MS or LC-MS/MS)
USEPA 8321B
(Dichloromethane extraction GC-MS or LC-MS/MS)
|
| Octabromodiphenyl ether (OctaBDE) |
32536-52-0
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Pentabromodiphenyl ether (PentaBDE) |
32534-81-9
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Polybromobiphenyls (PBB) |
59536-65-1
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Tetraboron disodium heptaoxide, hydrate |
12267-73-1
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
500
μg/L
Leather :
500
μg/L
Footwear :
500
μg/L
|
determined as total boron via ICP
|
| Tetrabromobisphenol A (TBBPA) |
79-94-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Tetrabromodiphenyl ether (TetraBDE) |
40088-47-9
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Tri-o-cresyl phosphate |
78-30-8
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Tribromodiphenylethers (TriBDEs) |
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Trimethyl phosphate |
512-56-1
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Tris(1,3-dichloro-isopropyl) phosphate (TDCP) |
13674-87-8
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Tris(1-aziridinyl)phosphine oxide (TEPA) |
545-55-1
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Tris(2,3,-dibromopropyl) phosphate (TRIS) |
126-72-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Tris(2-chloro-1-methylethyl) phosphate (TCPP) |
13674-84-5
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Tris(2-chloroethyl) phosphate (TCEP) |
115-96-8
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Trixylyl phosphate (TXP) |
25155-23-1
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
25
μg/L
Leather :
25
μg/L
Footwear :
25
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
|
| Glycols / Glycol Ethers | ||||||
| 2- methoxypropanol |
1589-47-5
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Leather :
50
μg/L
Footwear :
50
μg/L
|
USEPA 8270E
Liquid extraction, GC-MS , LC-MS
GB 38468-2019
DIN EN ISO 11890-2
HG/T 5700-2020
|
| 2-Methoxyethyl acetate |
110-49-6
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
50
μg/L
Textile :
50
μg/L
Footwear :
50
μg/L
|
USEPA 8270E
Liquid extraction, GC-MS , LC-MS
GB 38468-2019
DIN EN ISO 11890-2
HG/T 5700-2020
|
| 2-Methoxypropyl acetate |
70657-70-4
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
50
μg/L
Textile :
50
μg/L
Footwear :
50
μg/L
|
USEPA 8270E
Liquid extraction, GC-MS, LC-MS
GB 38468-2019
DIN EN ISO 11890-2
HG/T 5700-2020
|
| 2-ethoxyethanol |
110-80-5
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
50
μg/L
Textile :
50
μg/L
Footwear :
50
μg/L
|
USEPA 8270E
Liquid extraction, GC-MS, LC-MS
GB 38468-2019
HG/T 5700-2020
DIN EN ISO 11890-2
|
| 2-ethoxyethyl acetate |
111-15-9
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
50
μg/L
Textile :
50
μg/L
Footwear :
50
μg/L
|
USEPA 8270E
Liquid extraction, GC-MS, LC-MS
GB 38468-2019
HG/T 5700-2020
DIN EN ISO 11890-2
|
| 2-methoxyethanol |
109-86-4
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
50
μg/L
Textile :
50
μg/L
Footwear :
50
μg/L
|
USEPA 8270E
Liquid extraction, LC-MS, GC-MS
DIN EN ISO 11890-2
GB 38468-2019
HG/T 5700-2020
|
| Bis(2-methoxyethyl) ether |
111-96-6
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
50
μg/L
Textile :
50
μg/L
Footwear :
50
μg/L
|
USEPA 8270E
Liquid extraction, GC-MS, LC-MS
GB 38468-2019
DIN EN ISO 11890-2
HG/T 5700-2020
|
| Ethylene glycol dimethyl ether |
110-71-4
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
50
μg/L
Textile :
50
μg/L
Footwear :
50
μg/L
|
USEPA 8270E
Liquid extraction, GC-MS, LC-MS
DIN EN ISO 11890-2
GB 38468-2019
HG/T 5700-2020
|
| Triethylene glycol dimethyl ether |
112-49-2
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
50
μg/L
Textile :
50
μg/L
Footwear :
50
μg/L
|
USEPA 8270E
Liquid extraction, GC-MS, LC-MS
HG/T 5700-2020
GB 38468-2019
DIN EN ISO 11890-2
|
| Halogenated Solvents | ||||||
| 1,2-Dichloroethane |
107-06-2
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
1
μg/L
Textile :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8260D
Headspace GC/MS or Purge and trap GC/MS
EPA 5021
EPA 8021 B
GB/T 35446-2017 for textiles
DIN EN ISO 11890-2
EPA 8260 B
EPA 5030 C 2003 + EPA 8260 D 2017
DIN 38407-43 :2014
|
| Methylene chloride |
75-09-2
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
1
μg/L
Textile :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8260D
Headspace GC/MS or Purge and trap GC/MS
EPA 8021 B
EPA 5021
DIN 38407-43 :2014
GB/T 35446-2017 for textiles
DIN EN ISO 11890-2
EPA 8260 B
EPA 5030 C 2003 + EPA 8260 D 2017
|
| Tetrachloroethylene |
127-18-4
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
1
μg/L
Textile :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8260D
Headspace GC/MS or Purge and trap GC/MS
EPA 8021 B
EPA 5021
DIN 38407-43 :2014
DIN EN ISO 11890-2
EPA 8260 B
EPA 5030 C 2003 + EPA 8260 D 2017
GB/T 35446-2017 for textiles
|
| Trichloroethylene |
79-01-6
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
1
μg/L
Textile :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8260D
Headspace GC/MS or Purge and trap GC/MS
EPA 8021 B
EPA 5021
DIN 38407-43 :2014
DIN EN ISO 11890-2
GB/T 35446-2017 for textiles
EPA 5030 C 2003 + EPA 8260 D 2017
EPA 8260 B
|
| Organic Solvents | ||||||
| Benzene |
71-43-2
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
ISO 11423-1
Headspace or Purge and trap
USEPA 8260D
ISO 20595
Static headspace for determination of VOC in wastewater
|
| N,N-Dimethylacetamide (DMAC) |
127-19-5
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
(Sample and report)
μg/L
Leather :
(Sample and report)
μg/L
Footwear :
(Sample and report)
μg/L
|
Solid Phase Extraction (Active Carbon) followed by GC-MS
EPA 8015
Analysis by GC-MS
EPA 8270E
Analysis by GC-MS
EPA 3535- 2007
Determination GC-MS/MS
|
| If the detection is >5000 ug/L in untreated wastewater then this parameter is to be also tested in the discharged wastewater(effluent) applicable only for Direct discharge type of facilities. | ||||||
| N,N-dimethylformamide (DMFa) |
68-12-2
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
(Sample and report)
μg/L
Leather :
(Sample and report)
μg/L
Footwear :
(Sample and report)
μg/L
|
EPA 8015
EPA 8270E
ISO 16189
GB/T 33390
ISO/TS 16189-2013
|
| If the detection is >5000 ug/L in untreated wastewater then this parameter is to be also tested in the discharged wastewater(effluent) applicable only for Direct discharge type of facilities. | ||||||
| N-Ethyl-2 pyrrolidone (NEP) |
2687-91-4
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
(Sample and report)
μg/L
Leather :
(Sample and report)
μg/L
Footwear :
(Sample and report)
μg/L
|
EPA 8015
Analysis by GC-MS
EPA 8270E
Analysis by GC-MS
Solid Phase Extraction (Active Carbon) followed by GC-MS
EPA 3535- 2007
Determination GC-MS/MS
Solid Phase Microextraction (SPME)
|
| If the detection is >5000 ug/L in untreated wastewater then this parameter is to be also tested in the discharged wastewater(effluent) applicable only for Direct discharge type of facilities. | ||||||
| N-Methyl-2-Pyrrolidone (NMP) |
872-50-4
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
(Sample and report)
μg/L
Leather :
(Sample and report)
Footwear :
(Sample and report)
μg/L
|
EPA 8015
Analysis by GC-MS
EPA 8270E
Analysis by GC-MS
Solid Phase Extraction (Active Carbon) followed by GC-MS
EPA 3535- 2007
Determination GC-MS/MS
Solid Phase Microextraction (SPME)
|
| If the detection is >5000 ug/L in untreated wastewater then this parameter is to be also tested in the discharged wastewater(effluent) applicable only for Direct discharge type of facilities. | ||||||
| Sum of o,m, p- cresol |
108-39-4, 95-48-7, 106-44-5
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
ISO 11423-1
EPA 8270E
Analysis by GC-MS
BS EN 12673-1999
EPA 8015
Analysis by GC-MS
EPA 8270
Analysis by GC-MS (Headspace) or dichloromethane extraction (derivatisation with BSTFA & TMCs or acetic anhydride) followed by GC-MS
|
| Sum of o,m, p-xylene |
106-42-3, 95-47-6, 108-38-3
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
ISO 11423-1
Headspace or Purge and trap followed by GC-MS
USEPA 8260D
HJ 639
EPA 5021A
GC-MS Headspace
|
| Toluene |
108-88-3
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
HJ 1067
EPA 8260D
|
| Organotin Compounds | ||||||
| Dibutyltin (DBT) |
683-18-1
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.01
μg/L
Leather :
0.01
μg/L
Footwear :
0.01
μg/L
|
ISO 17353
Derivatisation with NaB (C2H5) GC-MS
DIN EN ISO 22744-1
|
| Dipropyltin compounds (DPT) |
867-36-7
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.01
μg/L
Textile :
0.01
μg/L
Footwear :
0.01
μg/L
|
ISO 17353
Derivatisation with NaB(C2H5) GC-MS
DIN EN ISO 22744-1
|
| Mono-, di- and tri- butyltin derivatives |
1118-46-3
1461-22-9
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.01
μg/L
Textile :
0.01
μg/L
Footwear :
0.01
μg/L
|
ISO 17353
Derivatisation with NaB(C2H5) GC-MS
DIN EN ISO 22744-1
|
| Mono-, di- and tri- methyltin derivatives |
1066-45-1
753-73-1
993-16-8
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.01
μg/L
Textile :
0.01
μg/L
Footwear :
0.01
μg/L
|
ISO 17353
Derivatisation with NaB(C2H5) GC-MS
DIN EN ISO 22744-1
|
| Mono-, di- and tri- octyltin derivatives |
2587-76-0
3091-25-6
3542-36-7
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.01
μg/L
Textile :
0.01
μg/L
Footwear :
0.01
μg/L
|
ISO 17353
Derivatisation with NaB(C2H5) GC-MS
DIN EN ISO 22744-1
|
| Mono-, di- and tri- phenyltin derivatives |
1124-19-2
1135-99-5
639-58-7
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.01
μg/L
Textile :
0.01
μg/L
Footwear :
0.01
μg/L
|
ISO 17353
Derivatisation with NaB(C2H5) GC-MS
DIN EN ISO 22744-1
|
| Tetrabutyltin Compounds (TeBT) |
1461-25-2
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.01
μg/L
Textile :
0.01
μg/L
Footwear :
0.01
μg/L
|
ISO 17353
Derivatisation with NaB(C2H5) GC-MS
DIN EN ISO 22744-1
|
| Tetraethyltin Compounds (TeET) |
597-64-8
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.01
μg/L
Textile :
0.01
μg/L
Footwear :
0.01
μg/L
|
ISO 17353
DIN EN ISO 22744-1
|
| Tetraoctyltin Compounds (TeOT) |
3590-84-9
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.01
μg/L
Textile :
0.01
μg/L
Footwear :
0.01
μg/L
|
ISO 17353
Derivatisation with NaB(C2H5) GC-MS
DIN EN ISO 22744-1
DIN EN ISO 22744-1
|
| Tricyclohexyltin (TCyHT) |
3091-32-5
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.01
μg/L
Textile :
0.01
μg/L
Footwear :
0.01
μg/L
|
ISO 17353
Derivatisation with NaB(C2H5) GC-MS
DIN EN ISO 22744-1
|
| Tripropyltin Compounds (TPT) |
2279-76-7
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
0.01
μg/L
Textile :
0.01
μg/L
Footwear :
0.01
μg/L
|
ISO 17353
Derivatisation with NaB(C2H5) GC-MS
DIN EN ISO 22744-1
|
| Other/Miscellaneous Chemicals | ||||||
| (Free) Aniline |
62-53-3
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
sample and report
μg/L
Leather :
sample and report
μg/L
Footwear :
sample and report
μg/L
|
ISO 14362-1
EPA 8270E
reference to azo dyes, do not need the reducing agent dithionate as we are looking at free aniline & not cleavable aniline
EN 71-11 : 2005
only the analysis method to be used without the reduction step
|
| AEEA (2-(2-Aminoethylamino)ethanol)) |
111-41-1
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
500
μg/L
Leather :
500
μg/L
Footwear :
500
μg/L
|
Liquid extraction LC-MSMS
ISO 12010:2019
ASTM D7742-2017
EPA 8021 B
|
| Bisphenol A (BPA) |
80-05-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
10
μg/L
Leather :
10
μg/L
Footwear :
10
μg/L
|
Liquid extraction LC-MS
ISO 12010:2019
ASTM D7742-2017
GB 4806.10-2016
USEPA 8321B
ISO 17881-2
DIN EN ISO 18254-1 LC-MS/MS
ASTM D 7574
|
| Borate, (total Borate) |
-
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
(Sample and report)
μg/L
Leather :
(Sample and report)
μg/L
Footwear :
(Sample and report)
μg/L
|
ICP
Determined as total Boron
|
| Borate, (total Zinc) |
-
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
(Sample and report)
μg/L
Textile :
(Sample and report)
μg/L
Footwear :
(Sample and report)
μg/L
|
ICP
Determined as total Zinc
|
| Borate, zinc salt - Result |
12767-90-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
500
μg/L
Leather :
500
μg/L
Footwear :
500
μg/L
|
ICP
Determined as total Boron and total Zinc
|
| Footnote for borate, zinc salt: Limit refers to boron and zinc individually, not the salt. | ||||||
| D4 (Octamethylcyclotetrasiloxane) |
556-67-2
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
(Sample and report)
μg/L
Leather :
(Sample and report)
μg/L
Footwear :
(Sample and report)
μg/L
|
ISO/DIS 23649
EPA 3510 C: 1996
GC-MS for Siloxanes
GB/T 40955
EPA 8270E: 2018 (SW-846)
ISO 20596-2
|
| D5 (Decamethylcyclopentasiloxane) |
541-02-6
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
sample and report
μg/L
Leather :
sample and report
μg/L
Footwear :
sample and report
μg/L
|
ISO/DIS 23649
EPA 8270E: 2018 (SW-846)
GC-MS for Siloxanes
GB/T 40955
EPA 8270E: 2018 (SW-846)
ISO 20596-2
|
| D6 (Dodecamethylcyclohexasiloxane) |
540-97-6
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
sample and report
μg/L
Leather :
sample and report
μg/L
Footwear :
sample and report
μg/L
|
ISO/DIS 23649
EPA 3510 C: 1996
GB/T 40955
ISO 20596-2
|
| Perboric acid, sodium salt |
11138-47-9
125022-34-6
13517-20-9
15120-21-5
16940-66-2
7632-04-04
90568-23-3
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
500
μg/L
Leather :
500
μg/L
Footwear :
500
μg/L
|
determined as total boron via ICP
Reference EN ISO 15587-2, EN ISO 11885 as well as ISO 17294-2:2023
|
| Quinoline |
91-22-5
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Leather :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
USEPA 8270E
Liquid extraction, GC-MS
DIN 54231: 2022
Direct aqueous injection followed by LC/MS/MS
ISO 12010:2019
ASTM D7742-2017
GB/T 31531-2015 (GC-MS)
USEPA 8321B
AFPS GS:01 PAK
DIN 54231 (textile) with the declaration & extraction of the sample
|
| Thiourea |
62-56-6
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
50
μg/L
Leather :
50
μg/L
Footwear :
50
μg/L
|
Liquid extraction LC-MS
USEPA 8270E
Liquid extraction, GC-MS
DIN 54231: 2022
Direct aqueous injection followed by LC/MS/MS
ISO 12010:2019
ASTM D7742-2017
USEPA 8321B
|
| Per- and Polyfluoroalkyl Substances (PFAS) | ||||||
| 10:2 Fluorotelomer alcohols (10:2 FTOH) |
865-86-1
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
Solvent extraction, derivatisation with acetic anhydride followed by GC-MS
Liquid extraction with DCM (dichloromethane) followed by GC/MS or GC/MS/MS
EM 201 or DIN 38407-42
CEN/TS 15968:2010
ISO 25101:2009
|
| 4:2 Fluorotelomer alcohols (4:2 FTOH) |
2043-47-2
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
Solvent extraction, derivatisation with acetic anhydride followed by GC-MS
Liquid extraction with DCM (dichloromethane) followed by GC/MS or GC/MS/MS
EM 201 or DIN 38407-42
CEN/TS 15968:2010
ISO 25101:2009
|
| 6:2 Fluorotelomer alcohols (6:2 FTOH) |
647-42-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
Solvent extraction, derivatisation with acetic anhydride followed by GC-MS
Liquid extraction with DCM (dichloromethane) followed by GC/MS or GC/MS/MS
ISO 25101:2009
CEN/TS 15968:2010
EM 201 or DIN 38407-42
|
| 8:2 Fluorotelomer alcohols (8:2 FTOH) |
678-39-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
Liquid extraction with DCM (dichloromethane) followed by GC/MS or GC/MS/MS
Solvent extraction, derivatisation with acetic anhydride followed by GC-MS
ISO 25101:2009
CEN/TS 15968:2010
EM 201 or DIN 38407-42
|
| Perfluorobutane sulfonic acid (PFBS) |
375-73-5
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
EN 17892
Direct Injection LC/MS/MS
ISO 25101
Direct Injection LC/MS/MS
DIN 38407-42
Direct Injection LC/MS/MS
ISO 25101:2009
CEN/TS 15968:2010
EM 201 or DIN 38407-42
ISO 21675 : 2019
|
| Any detection above 0.1 μg/L to be reported in the test report by the wastewater testing labs. | ||||||
| Perfluorobutanoic acid (PFBA) |
375-22-4
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
EN 17892
Direct Injection LC/MS/MS
ISO 25101
Direct Injection LC/MS/MS
DIN 38407-42
Direct Injection LC/MS/MS
ISO 25101:2009
CEN/TS 15968:2010
EM 201 or DIN 38407-42
|
| Any detection above 0.1 μg/L to be reported in the test report by the wastewater testing labs. | ||||||
| Perfluorodecane sulfonic acid (PFDS) |
335-77-3
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
EN 17892
Direct Injection LC/MS/MS
DIN 38407-42
Direct Injection LC/MS/MS
ISO 25101
CEN/TS 15968:2010
EM 201 or DIN 38407-42
ISO 25101:2009
|
| Any detection above 0.1 μg/L to be reported in the test report by the wastewater testing labs. | ||||||
| Perfluorodecanoic acid (PFDA) |
335-76-2
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
EN 17892
Direct Injection LC/MS/MS
DIN 38407-42
Direct Injection LC/MS/MS
ISO 25101
Direct Injection LC/MS/MS
ISO 25101:2009
EM 201 or DIN 38407-42
CEN/TS 15968:2010
|
| Any detection above 0.1 μg/L to be reported in the test report by the wastewater testing labs. | ||||||
| Perfluorohexane sulfonic acid (PFHxS) |
355-46-4
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
EN 17892
Direct Injection LC/MS/MS
DIN 38407-42
Direct Injection LC/MS/MS
ISO 25101
Direct Injection LC/MS/MS
ISO 25101:2009
CEN/TS 15968:2010
EM 201 or DIN 38407-42
|
| Any detection above 0.1 μg/L to be reported in the test report by the wastewater testing labs. | ||||||
| Perfluorohexanoic acid (PFHxA) and related substances |
307-24-4
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
EN 17892
Direct Injection LC/MS/MS
DIN 38407-42
Direct Injection LC/MS/MS
ISO 25101
Direct Injection LC/MS/MS
EM 201 or DIN 38407-42
ISO 25101:2009
CEN/TS 15968:2010
|
| Any detection above 0.1 μg/L to be reported in the test report by the wastewater testing labs. | ||||||
| Perfluorooctane sulfonic acid (PFOS) and related susbstances |
1763-23-1
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
1
μg/L
Textile :
1
μg/L
Footwear :
1
μg/L
|
EPA 537:2020
GC-MS
Derivatisation with KOH, acetic anhydride followed by GC-MS
HJ 1333:2023
solid phase extraction and LC-MS/MS
ISO 21675
Determination of PFAS in water using solid phase extraction and LC-MS/MS
ISO 25101:2009
CEN/TS 15968:2010
EM 201 or DIN 38407-42
|
| Any detection above 0.1 μg/L to be reported in the test report by the wastewater testing labs. | ||||||
| Perfluorooctanoic acid (PFOA) and related substances |
335-67-1
Multiple
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
1
μg/L
Textile :
1
μg/L
Footwear :
1
μg/L
|
EPA 537:2020
GC-MS
Derivatisation with KOH, acetic anhydride followed by GC-MS
ISO 21675
Determination of PFAS in water using solid phase extraction and LC-MS/MS
HJ 1333:2023
solid phase extraction and LC-MS/MS
CEN/TS 15968:2010
ISO 25101:2009
EM 201 or DIN 38407-42
|
| Any detection above 0.1 μg/L to be reported in the test report by the wastewater testing labs. | ||||||
| Phthalates – Including All Other Esters of Ortho-Phthalic Acid | ||||||
| 1,2-Benzenedicarboxylic acid, di-C6-8-branched and linear alkyl esters, C7-rich (DIHP) |
71888-89-6
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
10
μg/L
Textile :
10
μg/L
Footwear :
10
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS
ISO 18856
Dichloromethane extraction GC-MS
EPA 3510 C 1996 + EPA 8270 E 2017
DIN EN ISO 16181-1 for leather
CPSC-CH-C1001-09.4
|
| 1,2-Benzenedicarboxylic acid, di-C7-11-branched and linear alkyl esters (DHNUP) |
68515-42-4
68515-50-4
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
10
μg/L
Textile :
10
μg/L
Footwear :
10
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS
ISO 18856
Dichloromethane extraction GC-MS
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| 1,2-Benzenedicarboxylic acid, dihexyl ester, branched and linear |
68515-50-4
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
10
μg/L
Leather :
10
μg/L
Footwear :
10
μg/L
|
USEPA 8270E
ISO 18856
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| 1,2-Benzenedicarboxylic acid, dipentylester, branched and linear |
84777-06-0
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
10
μg/L
Leather :
10
μg/L
Footwear :
10
μg/L
|
ISO 18856
USEPA 8270E
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Bis(2-methoxyethyl) phthalate (DMEP) |
117-82-8
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
10
μg/L
Textile :
10
μg/L
Footwear :
10
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS
ISO 18856
Dichloromethane extraction GC-MS
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Butyl benzyl phthalate (BBP) |
85-68-7
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
10
μg/L
Textile :
10
μg/L
Footwear :
10
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS
ISO 18856
Dichloromethane extraction GC-MS
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Di(ethylhexyl) phthalate (DEHP) |
117-81-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
10
μg/L
Leather :
10
μg/L
Footwear :
10
μg/L
|
ISO 18856
Dichloromethane extraction GC-MS
USEPA 8270E
Dichloromethane extraction GC-MS
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Di-cyclohexyl phthalate (DCHP) |
84-61-7
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
10
μg/L
Textile :
10
μg/L
Footwear :
10
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS
ISO 18856
Dichloromethane extraction GC-MS
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Di-iso-butyl phthalate (DIBP) |
84-69-5
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
10
μg/L
Leather :
10
μg/L
Footwear :
10
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS
ISO 18856
Dichloromethane extraction GC-MS
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Di-iso-decyl phthalate (DIDP) |
26761-40-0
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
10
μg/L
Textile :
10
μg/L
Footwear :
10
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS
ISO 18856
Dichloromethane extraction GC-MS
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
|
| Di-iso-octyl phthalate (DIOP) |
27554-26-3
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
10
μg/L
Textile :
10
μg/L
Footwear :
10
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS
ISO 18856
Dichloromethane extraction GC-MS
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Di-isononyl phthalate (DINP) |
28553-12-0
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
10
μg/L
Leather :
10
μg/L
Footwear :
10
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS
ISO 18856
Dichloromethane extraction GC-MS
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Di-n-hexyl phthalate (DnHP) |
84-75-3
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
10
μg/L
Leather :
10
μg/L
Footwear :
10
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS
ISO 18856
Dichloromethane extraction GC-MS
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Di-n-octyl phthalate (DNOP) |
117-84-0
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
10
μg/L
Leather :
10
μg/L
Footwear :
10
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS
ISO 18856
Dichloromethane extraction GC-MS
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Di-n-pentylphthalates (DnPP) |
131-18-0
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
10
μg/L
Leather :
10
μg/L
Footwear :
10
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS
ISO 18856
Dichloromethane extraction GC-MS
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Di-n-propyl phthalate (DPRP) |
131-16-8
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
10
μg/L
Leather :
10
μg/L
Footwear :
10
μg/L
|
USEPA 8270E
Dichloromethane extraction GC-MS
ISO 18856
Dichloromethane extraction GC-MS
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Dibutyl phthalate (DBP) |
84-74-2
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
10
μg/L
Leather :
10
μg/L
Footwear :
10
μg/L
|
ISO 18856
Dichloromethane extraction GC-MS
USEPA 8270E
Dichloromethane extraction GC-MS
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Diethyl phthalate (DEP) |
84-66-2
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
10
μg/L
Leather :
10
μg/L
Footwear :
10
μg/L
|
ISO 18856
Dichloromethane extraction GC-MS
USEPA 8270E
Dichloromethane extraction GC-MS
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Diisohexyl phthalate |
71850-09-4
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
10
μg/L
Leather :
10
μg/L
Footwear :
10
μg/L
|
ISO 18856
USEPA 8270E
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Diisopentyl phthalates (DIPP) |
605-50-5
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
10
μg/L
Leather :
10
μg/L
Footwear :
10
μg/L
|
ISO 18856
Dichloromethane extraction GC-MS
USEPA 8270E
Dichloromethane extraction GC-MS
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Dinonyl phthalate (DNP) |
84-76-4
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
10
μg/L
Leather :
10
μg/L
Footwear :
10
μg/L
|
ISO 18856
Dichloromethane extraction GC-MS
USEPA 8270E
Dichloromethane extraction GC-MS
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| n-Pentyl-isopentyl phthalate |
776297-69-9
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
10
μg/L
Leather :
10
μg/L
Footwear :
10
μg/L
|
ISO 18856
USEPA 8270E
CPSC-CH-C1001-09.4
DIN EN ISO 16181-1 for leather
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Polycyclic Aromatic Hydrocarbons (PAHs) | ||||||
| Acenaphthene |
83-32-9
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8270E
Solvent extraction GC-MS
DIN 38407-39
Solvent extraction GC-MS
APAT 5080
DIN EN 17132 for textile
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Acenaphthylene |
208-96-8
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8270E
Solvent extraction GC-MS
DIN 38407-39
Solvent extraction GC-MS
APAT 5080
DIN EN 17132 for textile
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Anthracene |
120-12-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8270E
Solvent extraction GC-MS
DIN 38407-39
Solvent extraction GC-MS
APAT 5080
DIN EN 17132 for textile
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Benzo[a]anthracene |
56-55-3
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8270E
Solvent extraction GC-MS
DIN 38407-39
Solvent extraction GC-MS
APAT 5080
DIN EN 17132 for textile
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Benzo[a]pyrene (BaP) |
50-32-8
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8270E
Solvent extraction GC-MS
DIN 38407-39
Solvent extraction GC-MS
APAT 5080
DIN EN 17132 for textile
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Benzo[b]fluoranthene |
205-99-2
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8270E
Solvent extraction GC-MS
DIN 38407-39
Solvent extraction GC-MS
APAT 5080
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Benzo[e]pyrene |
192-97-2
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
1
μg/L
Textile :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8270E
Solvent extraction GC-MS
DIN 38407-39
Solvent extraction GC-MS
APAT 5080
DIN EN 17132 for textile
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Benzo[ghi]perylene |
191-24-2
|
Not Applicable | Not Applicable | Not Applicable |
Leather :
1
μg/L
Textile :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8270E
Solvent extraction GC-MS
DIN 38407-39
Solvent extraction GC-MS
APAT 5080
DIN EN 17132 for textile
DIN EN 17132 for textile
|
| Benzo[j]fluoranthene |
205-82-3
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8270E
Solvent extraction GC-MS
DIN 38407-39
Solvent extraction GC-MS
APAT 5080
DIN EN 17132 for textile
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Benzo[k]fluoranthene |
207-08-9
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8270E
Solvent extraction GC-MS
DIN 38407-39
Solvent extraction GC-MS
APAT 5080
DIN EN 17132 for textile
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Chrysene |
218-01-9
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8270E
Solvent extraction GC-MS
DIN 38407-39
Solvent extraction GC-MS
APAT 5080
DIN EN 17132 for textile
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Dibenz[a,h]anthracene |
53-70-3
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8270E
Solvent extraction GC-MS
DIN 38407-39
Solvent extraction GC-MS
APAT 5080
EPA 3510 C 1996 + EPA 8270 E 2017
DIN EN 17132 for textile
|
| Fluoranthene |
206-44-0
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8270E
Solvent extraction GC-MS
DIN 38407-39
Solvent extraction GC-MS
APAT 5080
DIN EN 17132 for textile
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Fluorene |
86-73-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8270E
Solvent extraction GC-MS
DIN 38407-39
Solvent extraction GC-MS
APAT 5080
EPA 3510 C 1996 + EPA 8270 E 2017
DIN EN 17132 for textile
|
| Indeno[1,2,3-cd]pyrene |
193-39-5
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8270E
Solvent extraction GC-MS
DIN 38407-39
Solvent extraction GC-MS
APAT 5080
DIN EN 17132 for textile
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Naphthalene |
91-20-3
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8270E
Solvent extraction GC-MS
DIN 38407-39
Solvent extraction GC-MS
APAT 5080
DIN EN 17132 for textile
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Phenanthrene |
85-01-8
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8270E
Solvent extraction GC-MS
DIN 38407-39
Solvent extraction GC-MS
APAT 5080
DIN EN 17132 for textile
EPA 3510 C 1996 + EPA 8270 E 2017
Equivalant
|
| Pyrene |
129-00-0
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
1
μg/L
Leather :
1
μg/L
Footwear :
1
μg/L
|
USEPA 8270E
Solvent extraction GC-MS
DIN 38407-39
Solvent extraction GC-MS
APAT 5080
DIN EN 17132 for textile
EPA 3510 C 1996 + EPA 8270 E 2017
|
| Restricted Aromatic Amines (Cleavable from Azo-Colourants) | ||||||
| 2,4,5-Trimethylaniline |
137-17-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 2,4,5-trimethylaniline hydrochloride |
21436-97-5
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 2,4-Diaminoanisol |
615-05-4
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 2,4-Toluenediamine |
95-80-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 2,4-Xylidine |
95-68-1
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 2,6-Xylidine |
87-62-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 2-Naphthylamine |
91-59-8
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 2-Naphthylammoniumacetate |
553-00-4
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 3,3'-Dichlorobenzidine |
91-94-1
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 3,3-Dimethoxylbenzidine |
119-90-4
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 3,3-Dimethylbenzidine |
119-93-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 4,4'-Methylene-bis-(2-chloroaniline) |
101-14-4
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 4,4'-Methylenedi-o-toluidine |
838-88-0
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 4,4'-Oxydianiline |
101-80-4
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 4,4'-Thiodianiline |
139-65-1
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 4,4-Methylenedianiline |
101-77-9
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 4-Aminoazobenzene |
60-09-3
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 4-Aminodiphenyl |
92-67-1
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 4-Chloro-o-toluidine |
95-69-2
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 4-Chloroaniline |
106-47-8
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| P-Chloroaniline (PCA) has historically been used in the manufacture of dyes, pigments and other industrial chemicals. PCA is a carcinogenic amine that can be released from certain restricted dyes by reductive azo cleavage. It can also be present as a very low level contaminant in non-restricted dyes that do not release it via reductive azo cleavage. Deliberate use of PCA or dyes that are known to release PCA is not permitted and there is a limit in the ZDHC MRSL of 150 ppm. However, the use of conformant formulations with PCA below this limit value may occasionally result in PCA detections in untreated effluent, particularly where a facility has dyed a large number of black or dark shades over a relatively short period of time. If PCA is detected in wastewater and it is confirmed that the dye inventory is ZDHC MRSL conformant, it is advisable to liaise with dye suppliers to seek the lowest PCA content or PCA-free option for dyes such as reactive Black 5, which are used in large quantities and can be the source of PCA. | ||||||
| 4-chloro-o-toluidinium chloride |
3165-93-3
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 4-methoxy-m-phenylene diammonium sulphate;2,4-diaminoanisole sulphate |
39156-41-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 4-methoxy-m-phenylenediamine |
615-05-04
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 4-methyl-m-phenylenediamine |
95-80-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 5-nitro-o-toluidine |
99-55-8
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| 6-methoxy-m-toluidine |
120-71-8
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| Benzidine |
92-87-5
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| o-Aminoazotoluene |
97-56-3
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| o-Anisidine |
90-04-0
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| o-Toluidine |
95-53-4
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
0.1
μg/L
Leather :
0.1
μg/L
Footwear :
0.1
μg/L
|
USEPA 8270E
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-1
Reduction step with sodium dithionite, Solvent extraction with GC/MS or LC MS/MS
ISO 14362-3
GC/MS or LC MS/MS
|
| UV Absorbers | ||||||
| 2,4-Di-tert-butyl-6-(5-chlorobenzotriazole-2-yl) phenol (UV-327) |
3864-99-1
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
100
μg/L
Leather :
100
μg/L
Footwear :
100
μg/L
|
US EPA 8270
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 12010:2019
ASTM D7742-2017
|
| 2-(2H-benzotriazol-2-yl)-4,6-ditertpentylphenol (UV-328) |
25973-55-1
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
100
μg/L
Leather :
100
μg/L
Footwear :
100
μg/L
|
US EPA 8270
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 12010:2019
ASTM D7742-2017
|
| 2-(2H-benzotriazol-2-yl)-4-(tert-butyl)-6-(sec-butyl) phenol(UV-350) |
36437-37-3
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
100
μg/L
Leather :
100
μg/L
Footwear :
100
μg/L
|
US EPA 8270
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 12010:2019
ASTM D7742-2017
|
| 2-Benzotriazol-2-yl-4,6-di-tert-butylphenol (UV-320) |
3846-71-7
|
Not Applicable | Not Applicable | Not Applicable |
Textile :
100
μg/L
Leather :
100
μg/L
Footwear :
100
μg/L
|
US EPA 8270
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 527
Dichloromethane extraction GC-MS or LC-MS/MS
USEPA 8321B
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 22032
Dichloromethane extraction GC-MS or LC-MS/MS
ISO 12010:2019
ASTM D7742-2017
|
Discharged wastewater Requirements
Discharged wastewater: Arsenic (As)
| Substance / Parameter | CAS NO | Foundational Limit | Progressive Limit | Aspirational Limit | Limit Value | Test Method |
|---|---|---|---|---|---|---|
| Arsenic (As) |
7440-38-2
|
Textile :
(Sample and report)
mg/L
Leather :
(Sample and report)
mg/L
Footwear :
(Sample and report)
mg/L
|
Textile :
(Sample and report)
mg/L
Leather :
(Sample and report)
mg/L
Footwear :
(Sample and report)
mg/L
|
Textile :
(Sample and report)
mg/L
Leather :
(Sample and report)
mg/L
Footwear :
(Sample and report)
mg/L
|
ISO 17294
USEPA 200.8
USEPA 6010C
USEPA 6020A
HJ 700
IS 3025 (Part 65)
HJ 694
APHA 3030 APHA 23rd edition
APHA 3120B
APHA 3120B
APAT 3020
IS 3025 (Part 37)
|
Discharged wastewater: Cadmium (Cd)
| Substance / Parameter | CAS NO | Foundational Limit | Progressive Limit | Aspirational Limit | Limit Value | Test Method |
|---|---|---|---|---|---|---|
| Cadmium (Cd) |
7440-43-9
|
Textile :
(Sample and report)
mg/L
Leather :
(Sample and report)
mg/L
Footwear :
(Sample and report)
mg/L
|
Textile :
(Sample and report)
mg/L
Leather :
(Sample and report)
mg/L
Footwear :
(Sample and report)
mg/L
|
Textile :
(Sample and report)
mg/L
Leather :
(Sample and report)
mg/L
Footwear :
(Sample and report)
mg/L
|
ISO 17294
USEPA 200.8
USEPA 6010C
USEPA 6020A
GB 7475
HJ 700
IS 3025 (Part 65)
AAS Instrumental Method
IS 3025 (Part 41)
AAS Instrumental Method
APHA 3120B
APHA 3030 APHA 23rd edition
APAT 3020
|
Discharged wastewater: Chromium (VI)
| Substance / Parameter | CAS NO | Foundational Limit | Progressive Limit | Aspirational Limit | Limit Value | Test Method |
|---|---|---|---|---|---|---|
| Chromium (VI) |
18540-29-9
|
Textile :
(Sample and report)
mg/L
Leather :
(Sample and report)
mg/L
Footwear :
(Sample and report)
mg/L
|
Textile :
(Sample and report)
mg/L
Leather :
(Sample and report)
mg/L
Footwear :
(Sample and report)
mg/L
|
Textile :
(Sample and report)
mg/L
Leather :
(Sample and report)
mg/L
Footwear :
(Sample and report)
mg/L
|
ISO 18412
USEPA 218.6
GB 7467
IS 3025 (Part 52)
Must meet reporting limit
ISO 17075
USEPA 7199
APHA 3500 Cr B
APAT 3020
|
Discharged wastewater: Lead (Pb)
| Substance / Parameter | CAS NO | Foundational Limit | Progressive Limit | Aspirational Limit | Limit Value | Test Method |
|---|---|---|---|---|---|---|
| Lead (Pb) |
7439-92-1
|
Textile :
(Sample and report)
mg/L
Leather :
(Sample and report)
mg/L
Footwear :
(Sample and report)
mg/L
|
Textile :
(Sample and report)
mg/L
Leather :
(Sample and report)
mg/L
Footwear :
(Sample and report)
mg/L
|
Textile :
(Sample and report)
mg/L
Leather :
(Sample and report)
mg/L
Footwear :
(Sample and report)
mg/L
|
ISO 17294
USEPA 200.8
USEPA 6010C
USEPA 6020A
HJ 700
IS 3025 (Part 65)
AAS Instrumental Method
IS 3025 (Part 47)
AAS Instrumental Method
GB 7475
APHA 3120B
APHA 3030 APHA 23rd edition
APAT 3020
|
Discharged wastewater: Mercury (Hg)
| Substance / Parameter | CAS NO | Foundational Limit | Progressive Limit | Aspirational Limit | Limit Value | Test Method |
|---|---|---|---|---|---|---|
| Mercury (Hg) |
7439-97-6
|
Textile :
(Sample and report)
mg/L
Leather :
(Sample and report)
mg/L
Footwear :
(Sample and report)
mg/L
|
Textile :
(Sample and report)
mg/L
Leather :
(Sample and report)
mg/L
Footwear :
(Sample and report)
mg/L
|
Textile :
(Sample and report)
mg/L
Leather :
(Sample and report)
mg/L
Footwear :
(Sample and report)
mg/L
|
ISO 17294
EPA 200.8-SIM
EPA 6020A-SIM
EPA 245.1
EPA 245.7
HJ 597
HJ 694
IS 3025 (Part 48)
Cold Vapour AAS only
IS 3025 (Part 65)
ISO 11885
APHA 3120B
APHA 3030 APHA 23rd edition
APHA 3125 B
ISO 17852
EPA 7470 A
UNI EN ISO 12846:2013
APAT 3020
|